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CURRICULUM VITAE
Dr. Ilfir R. Ramazanov
Laboratory of Catalytic Synthesis, Institute of Petrochemistry and Catalysis,
pr. Oktyabrya 141, Ufa, 450075, Russia
E-mail: chemelf@hotbox.ru, Tel.: +7 (3472) 313527 (work),
Fax.: +7 (3472) 312750
1994-1998
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Ph.D. in Organic Chemistry "Hydro- and Cycloalumination of Disubstituted
Alkynes by Trialkyl- and Alkylhaloaluminium in the Presence of Metallocomplex Catalysts" |
1989-1994
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M.S. in Chemistry Prof. R.F. Talipov, Chemistry Department, Bashkir State University, Ufa, Russia.
"Investigation of Prins Reaction with Allyl
Esters in Sulphuric Acid Media"
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2005/09-present |
Senior Research ScientistProf. U.M. Dzhemilev, Institute of
Petrochemistry and Catalysis of Russian Academy of Sciences, Ufa, Russia.
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2003/02-2004/08 |
Research ScholarProf. Ei-ichi Negishi , Chemistry Department, Purdue University, West Lafayette, Indiana, USA.
Organometallic chemistry: Enantioselective carboalumination. (NMI)2ZrCl2 catalyzed enantioselective carboalumination of a,w-dienes and haloalkenes was studied.
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2001/10-2002/09 |
Post Doctoral fellowship of The Council for Higher Education in IsraelProf. J.T. Klug, Institutes for Applied Research, Ben-Gurion University of the Negev, Beer-Sheva, Israel.
Organic synthesis: Fluorescent markers for biological systems. Synthesized new fluorescent markers for protein structure studying based on pyrene and naphthalene derivatives.
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2000/03-2001/09 |
Senior Research ScientistProf. U.M. Dzhemilev, Institute of Petrochemistry
and Catalysis of Ufa Research Centre of the Russian Academy of Sciences, Ufa, Russia. Organometallic chemistry: Cyclic carboalumination of alkynes; Reactions of cyclic organoaluminium compounds; Cyclopropanation of alkynes; Radical hydroalkylation of alkenes. Developed reactions of 2,3-disubstituted aluminacyclopent-2-enes to prepare 1,1-disubstituted cyclopropanes; Alkyne cyclopropanation by CH2I2-Et3Al reagent was realized; Cp2TiCl2 catalyzed hydroalkylation of alkenes by t-BuBr.
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1998/12-2000/03 |
Research ScientistProf. U.M. Dzhemilev, Institute of Petrochemistry
and Catalysis of Ufa Research Centre of the Russian Academy of Sciences, Ufa, Russia. Organometallic chemistry: Cycloalumination of alkynes; First synthesis of aluminacyclopropenes and new approach to preparation of aluminacyclopentadienes.
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Focused toward to the following:
(i) Development of new synthetic procedures based on application of organometallic reagents and/or metallocomplex catalysts. Currently it includes reactions of organometallic compounds of Al, Mg and Li with substrates containing double and triple carbon-carbon bond catalyzed by Zr, Ti, Pd and Ni complexes.
(ii) Enantioselective addition to double carbon-carbon bond induced by chiral complexes of transition metals. Computational modelling of chiral transitions states for preliminary screening of enantioselective catalysts.
- Synthesis and handling of air- and moistsensitive compounds
- Chemistry of organoaluminium, -lithium, -magnesium and -sodium compounds (preparation and reactions)
- Chemistry of Ti-, Zr-, Ni- and Pd complexes with chiral ligands
- Chemistry of pyrene and naphthalene
Instrumental techniques:
- Separation (analytical and preparative GC-FID/TCD, TLC, HPLC, flash chromatography)
- Structural analysis (FT-NMR (Varian Gemini-200, Varian Mercury-300), FT-IR, enantiomeric excess estimation by Mosher method (MTPA esters))
- Reaction mechanism (low-temperature FT-NMR)
Computational techniques:
- Correlated Hartree-Fock and DFT calculations
- Calculations of reaction energies and reaction barriers
Computer skills:
- SciFinder, Belstein Crossfire, ChemOffice, ISIS Draw, HP Chemstation, ACDLab
- Gaussian, Gamess, Mopac, Spartan, Titan, Tinker, Hyperchem
- Word, Excel, Access, EndNote, SigmaPlot, Origin
- Delphi, Fortran, Pascal, C, Basic, Assembly language, HTML
- Windows, MS-DOS, Sun OS
Language:
- Russian (native language)
- English (fluently speaking, reading and writing)
- German (reading and writing)
- French (basic knowledge)
Organizing and writing:
- Supervising over the group of three PhD students (planning, writing)
2001-2002 |
Post Doctoral fellowship of The Council for Higher Education in IsraelInstitutes for Applied Research, Ben-Gurion University of the Negev, Beer-Sheva, Israel
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1997 |
Scholarship of the International Soros Science Educational Program (Soros postgraduate student) Institute of Petrochemistry and Catalysis of Ufa Research Centre of the Russian Academy of Sciences
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1996 |
Scholarship of Bashkortostan Republic GovernmentInstitute of Petrochemistry and Catalysis of Ufa Research Centre of the Russian Academy of Sciences
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- Russian Foundation of Basic Research (RFBR) Grant "New approaches to cyclopropane synthesis " (2001-2003)
- INTAS grant "Double asymmetric induction in reactions with chiral complexes of transition metals" (2000-2001)
- Russian Foundation of Basic Research (RFBR) Grant "Leading russian scientific schools" (2000-2002)
- Russian Foundation of Basic Research (RFBR) Grant "Synthesis and selective functionalization of carbon- and metal-containing cluster compounds" (2000-2002)
- Russian Foundation of Basic Research (RFBR) Grant " Development of new hydrometallation reagents for regio- and stereoselective reduction of alkenes and alkynes" (1998-2000)
- Russian Foundation of Basic Research (RFBR) Grant "Development of methods of metallacyclopropane synthesis based on Mg and Al compounds in the presence of metallocomplex catalysts" (1997-1999)
- Fund of support of scientific schools "Metallocomplex catalysis in organic and organometallic synthesis" sponsored by the Russian Foundation of Basic Researches (1996-1997)
2002 |
Member of the Israel Chemical Society
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- U. M. Dzhemilev, I. R. Ramazanov. "Ethylaluminium dichloride" //EROS. (prepared for publication)
- I. R. Ramazanov, A. Z. Sharipova, U. M. Dzhemilev. "13C NMR study of terminal alkyne hydroalumination"· (prepared for publication)
- I. R. Ramazanov, A. Z. Sharipova, U. M. Dzhemilev. "Cp2TiCl2-catalyzed hydroalkylation of cycloalkenes with ButBr-Et3Al" //Russ. J. Org. Chem.. (submitted for publication)
- I. R. Ramazanov, T. Novak, E.-i. Negishi. "Zr-catalyzed enantioselective carboalumination of a,w-dienes" // J. Am. Chem. Soc. (submitted for publication).
- I. R. Ramazanov, L. I. Djyatchenko, A. G. Ibragimov, U. M. Dzhemilev. "Cp2TiCl2-catalyzed hydroalkylation of alpha-olefins with ButBr-Et3Al"· //Russ. Chem. Bull., 51 (5), P.833-835, MAY 2002
- U. M. Dzhemilev, A. G. Ibragimov, L. O. Khafizova, I. R. Ramazanov, D. F. Yalalova, G. A. Tolstikov."One-pot synthesis of 1,1-disubstituted cyclopropanes in the presence of metal complex catalysts" //J. Organomet. Chem., 636 (1-2), P.76-81, Sp. Iss. SI NOV 25 2001
- U. M. Dzhemilev, I. R. Ramazanov, A. G. Ibragimov, M. P. Lukjyanova, L. I. Djyatchenko, O. M. Nefedov. "Acetylene cyclopropanation by CH2I2-Et3Al Reagent" //J. Organomet. Chem., 636 (1-2), P.91-95, Sp. Iss. SI NOV 25 2001
- I. R. Ramazanov, M. P. Lukjyanova, A. Z. Sharipova, A. G. Ibragimov, U. M. Dzhemilev, O. M. Nefedov. "One-step cyclopropanation of alkynes by CH2I2 and Et3Al" //Russ. Chem. Bull., 50:(8), P.1406-1409, AUG 2001
- U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, M. P. Lukjyanova, A. Z. Sharipova. "Zr-catalyzed cycloalumination of asymmetric disubstituted acetylenes" //Russ. Chem. Bull., 50:(3), P.484-487, MAR 2001
- U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, M. P. Lukjyanova, A. Z. Sharipova, L. M. Khalilov. "A novel method to synthesize 1,1-alkylcyclopropanes" //Russ. Chem. Bull, 49:(6), P. 1086-1089, JUN 2000
- A. G. Ibragimov, I. R. Ramazanov, L. M. Khalilov, U. M. Dzhemilev. "Aluminacyclopropenes, a novel series of organoaluminum compounds" // Russ. Chem. Bull., 46: (12), P. 2150-2152, DEC 1997.
- R. R. Muslukhov, L. M. Khalilov, I. R. Ramazanov, A. Z. Sharipova, A. G. Ibragimov, U. M. Dzhemilev. "NMR 13C spectra and electronic structure of alkenylalanes" //Russ. Chem. Bull., 46: (12), P. 2082-2085, DEC 1997.
- A. G. Ibragimov, I. R. Ramazanov, L. M. Khalilov, R. M. Sultanov, U. M. Dzhemilev. "Regio- and stereoselective hydroalumination of disubstituted acetylenes with Et3Al catalysed by Cp2TiCl2" //Mendeleev Commun., 6, P.231-232, NOV 1996.
- U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, R. M. Sultanov, L. M. Khalilov, R. R. Muslukhov. "Bui2AlCl-Cp2TiCl2 - A new reagent for hydroalumination of disubstituted acetylenes" //Russ. Chem. Bull., 45: (11), P. 2610-2613, NOV 1996.
RECENT PRESENTATIONS
- I.R. Ramazanov, E.-i. Negishi. "Zr-Catalyzed Enantioselective Carboalumination of a,w-dienes"//The 21st Herbert C. Brown Lectures in Organic Chemistry, Organometallics in Organic Synthesis, April 3, 2004.
- I.R. Ramazanov, J.T. Klug, V. Khodorkovsky "Theoretical study on electrophylic substitution in pyrene"//The 67th meeting of the Israel chemical society, Jerusalem, Israel, January 29-30, 2002.
The total number of journal publications and patents is 41.